PROSPECTING GUIDELINES FOR CHROMITE DEPOSITS

Geophysical Applications

Stratiform:

1. Identify well layered mafic-ultramafic intrusions;

2. Prospect below the mafic cumulate portions of the intrusions (i.e. below the portion which

is completely gabbroic).

Podiform:

1. Carefully prospect within all dunitic portions of Alpine-type peridotites (Harzburgite-Dunite

 components of ophiolite complexes).

 

METHODS

Geophysical

Since Podiform deposits are irregular in shape and unpredictable, gravity and electrical methods

may offer some promise as exploration tools. Some geophysical methods, such as gamma-ray

spectrometry and remote sensing, measure surface attributes; others, such as thermal and

some electrical methods are limited to detecting relatively shallow features but may help identify

features at greater depth. Secondary effects of deeper features, such as geochemical haloes, 

can often be identified by these methods as given in Table 3.

 

Gravity method

Gravity measurements define anomalous density within the Earth. In most cases, groundbased

gravimeters are used to precisely measure variations in the gravity field at different

points. Gravity anomalies are computed by subtracting a regional field from the measured

field, which result in gravitational anomalies that correlate with source body density variations.

Positive gravity anomalies are associated with shallow high density

bodies, whereas gravity

lows are associated with shallow low density bodies. Thus, deposits of high-density chromite,

hematite, and barite yield gravity highs, whereas deposits of low-density halite, weathered

kimberlite, and diatomaceous earth yield gravity lows. The gravity method also enables a

prediction of the total anomalous mass (ore tonnage) responsible for an anomaly. Gravity and

magnetic (discussed below) methods detect only lateral contrasts in density or magnetization,

respectively. In contrast, electrical and seismic methods can detect vertical, as well as lateral

contrasts of resistivity and velocity or reflectivity.

Applications of gravity method for mineral deposit environmental considerations

includes identification of lithologies, structures, and, at times, orebodies themselves (Wright,

1981). Small anomalous bodies, such as underground workings, are not easily detected by

gravity surveys unless they are at shallow depth.


Magnetic method

The magnetic method exploits small variations in magnetic mineralogy (magnetic iron and

iron-titanium oxide minerals, including magnetite, titanomagnetite, titanomaghemite, and

titanohematite, and some iron sulfide minerals, including pyrrhotite and greigite) among rocks.

Measurements are made using fluxgate, proton-precession, Overhauser, and optical absorption

magnetometers. In most cases, total-magnetic field data are acquired; vector measurements

are made in some instances. Magnetic rocks contain various combinations of induced and

remanent magnetization that perturb the Earth’s primary field (Reynolds and others, 1990).

The magnitudes of both induced and remanent magnetization depend on the quantity,

composition and size of magnetic-mineral grains.

Magnetic anomalies may be related to primary igneous or sedimentary processes that

establish the magnetic mineralogy, or they may be related to secondary alteration that either

introduces or removes magnetic minerals. In mineral exploration and its geo-environmental

considerations, the secondary effects in rocks that host ore deposits associated with

hydrothermal systems are important (Hanna, 1969; Criss and Champion, 1984) and magnetic

surveys may outline zones of fossil hydrothermal activity. Because rock alteration can effect a

change in bulk density as well as magnetization, magnetic anomalies, when corrected for

magnetization direction, sometimes coincide with gravity anomalies.

Magnetic exploration may directly detect some iron ore deposits (magnetite or banded

iron formation), and magnetic methods often are useful for deducing subsurface lithology and

structure that may indirectly aid identification of mineralized rock, patterns of effluent flow,

and extent of permissive terranes and (or) favorable tracts for deposits beneath surficial cover.

Geo-environmental applications may also include identification of magnetic minerals associated

with ore or waste rock from which hazardous materials may be released. Such associations

permit the indirect identification of hazardous materials such as those present in many nickelcopper or

serpentine hosted asbestos deposits.

 

Gamma-ray methods

Gamma-ray methods (Durrance, 1986; Hoover and others, 1991) use scintillometry to identify

the presence of the natural radio elements potassium, uranium, and thorium; multi-channel

spectrometers can provide measures of individual radioelement abundances. Gamma-ray

methods have had wide application in uranium exploration because they provide direct

detection. Thorium is generally the most immobile of the three radio elements and has

geochemical behavior similar to that of zirconium. Thorium content, like uranium content,

tends to increase in felsic rocks and generally increases with alkalinity.

Gamma-ray spectrometry, because it can provide direct quantitative measures of the

natural radio elements, provides geo-environmental information concerning radiation dose

and radon potential. Because uranium and (or) potassium are commonly enriched in or adjacent

to some deposits, their presence may often be used to indirectly assess the potential for release

of hazardous materials from ore or waste piles. Where sulfide minerals are present their

oxidation accelerates uranium mobilization.

 

Seismic methods

Seismic techniques have had relatively limited utilization, due to their relatively high cost and

the difficulty of acquiring and interpreting seismic data in strongly faulted and altered igneous

terranes, in mineral assessments and exploration at the deposit scale. However, shallow seismic surveys

employ less expensive sources and smaller surveys than that of regional surveys, and the cost of

studying certain geo-environmental problems in the near subsurface may not be prohibitive. Reflection

seismic methods provide fine structural detail and refraction methods provide precise estimates of depth

to lithologies of differing acoustic impedance. The refraction method has been used in mineral

investigations to map low-velocity alluvial deposits such as those that may contain gold, tin, or sand and

gravel. Applications in geo-environmental work include studying the structure, thickness, and

 hydrology of tailings and extent of acid mine drainage around mineral deposits (Dave and others,

 1986).

 

Thermal methods

Two distinct techniques are included under thermal methods (Table 3): (a) borehole or shallow

probe methods for measuring thermal gradient, which is useful itself, and with a knowledge of

the thermal conductivity provides a measure of heat flow, and (b) airborne or satellite-based

measurements, which can be used to determine the Earth’s surface temperature and thermal

inertia of surficial materials, of thermal infrared radiation emitted at the Earth’s surface.

Thermal noise includes topography, variations in thermal conductivity, and intrinsic

endothermic and exothermic sources.

Borehole thermal methods have been applied in geothermal exploration, but have seldom

been used in mineral exploration. However, this method has potential usefulness in exploration

and in geo-environmental investigations (Ovnatanov and Tamrazyan, 1970; Brown and others,

1980; Zielinski and others, 1983; Houseman and others, 1989). Causes of heat flux anomalies

include oxidizing sulfide minerals and high radioelement concentrations. Conditions that may

focus, or disperse, heat flow are hydrologic and topographic influences, as well as anomalous

thermal conductivity. In geo-environmental applications, oxidation of sulfide bodies in-place

or on waste piles, if sufficiently rapid, can generate measurable thermal anomalies, which can

provide a measure of the amount of metal being released to the environment. Borehole

temperatures may also reflect hydrologic and hydrothermal systems that have exploration

and geo-environmental consequences. Airborne thermal infra-red measurements have

applications in geothermal exploration, and may have potential in mineral exploration and in

geo-environmental applications whenever ground surface temperature is anomalous due to

sulfide oxidation, hydrologic conditions, or heat-flow perturbations due to structure or lithology

(Strangway and Holmer, 1966).

Thermal infra-red imaging methods are a specialized branch of more generalized remote

sensing techniques. Images obtained in this wavelength range may be used for photo-geologic

interpretation or, if day and night images are available, to estimate the thermal inertia of the

surface. Unconsolidated or glassy materials can be distinguished by their low thermal inertia.

In places, thermal infra-red images can distinguish areas of anomalous silicification (Watson

and others, 1990).

 

Electrical methods

Electrical methods comprise a multiplicity of separate techniques that employ differing

instruments and procedures, have variable exploration depth and lateral resolution, and are

known by a large lexicon of names and acronyms describing techniques and their variants.

Electrical methods can be described in five classes: (1) direct current resistivity, (2)

electromagnetic, (3) mise-a-la-masse, (4)Self potential, and (5) Induced Polarization Method.

In spite of all the variants, measurements fundamentally are of the Earth’s electrical impedance

or relate to changes in impedance. Electrical methods have broad application to mineral and geo-

environmental problems. They may be used to identify sulfide minerals, are directly applicable to

 hydrologic investigations, and can be used to identify structures and lithologies.

 

Direct current resistivity method

Direct current resistivity method measure Earth resistivity (the inverse of conductivity) using a

direct or low frequency alternating current source. Rocks are electrically conductive as

consequences of ionic migration in pore space water and more rarely, electronic conduction

through metallic lustre minerals. Because metallic lustre minerals typically do not provide

long continuous circuit paths for conduction in the host rock, bulk-rock resistivities are almost

always controlled by water content and dissolved ionic species present. High porosity causes

low resistivity in water-saturated rocks.

Direct current techniques have application to a variety of mineral exploration and geoenvironmental

 considerations related to various ore deposit types. Massive sulfide deposits

are a direct low resistivity target, whereas clay alteration assemblages are an indirect low

resistivity target within and around many hydrothermal systems. The wide range of earth

material resistivities also makes the method applicable to identification of lithologies and

structures that may control mineralization. Acid mine waste, because of high hydrogen ion

mobility, provides a more conductive target than solutions containing equivalent concentrations

of neutral salts.

 

Electromagnetic method

Electromagnetic measurements use alternating magnetic fields to induce measurable current

in the Earth. The traditional application of electromagnetic methods in mineral exploration

has been in the search for low-resistivity (high-conductivity) massive sulfide deposits. Airborne

methods may be used to screen large areas and provide a multitude of targets for ground

surveys. Electromagnetic methods, including airborne, are widely used to map lithologic and

structural features (Palacky, 1986; Hoover and others, 1991) from which various mineral

exploration and geo-environmental inferences are possible.

 

Mise-a-la-masse method

The mise-a-la-masse method is a little used technique applied to conductive masses that have

large resistivity contrasts with their enclosing host rock. In exploration, application of this

method is principally in mapping massive sulfide deposits. This method is useful in geoenvironmental

 investigations of highly conductive targets; it has been applied to identify a contaminant plume

 emanating from an abandoned mine site (Osiensky and Donaldson, 1994).

 

Self potential method

Several possible natural sources generate measurable direct current or quasi-direct current,

natural electrical fields or self potentials. The association of a self potential anomaly with a

sulfide deposit indicates a site of ongoing oxidation and that metals are being mobilized; other

self potential anomalies are due to fluxes of water or heat through the Earth (Corwin, 1990).

Geo-environmental applications include searching for zones of oxidation and paths of ground

water movement.

 

Induced polarization method

The induced polarization method provides a measure of polarizable minerals (metallic-luster sulfide

 minerals, clays, and zeolites) within water-bearing pore spaces of rocks. Polarizable minerals, in order

 to be detected, must present an active surface to pore water. Because induced polarization responses

 relate to active surface areas within rocks, disseminated sulfide minerals provide a much better target

 for this method than massive sulfide deposits, although in practice most massive sulfide deposits have

 significant gangue and have measurable induced polarization. Induced polarization has found its

 greatest application in exploration for disseminated sulfide ore, where it may detect as little as 0.5

 volume percent total metallic lustre sulfide minerals (Sumner, 1976). In geo-environmental studies,

 induced polarization surveys are principally used to identify sulfide minerals, but it may have other

 applications, such as outlining clay aquitards that can control mine effluent flow.

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